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2025諾獎視角下的MOF合成革新：微波合成技術(shù)在MOF中的應(yīng)用2025年諾貝爾化學(xué)獎授予金屬有機(jī)框架（MOFs）相關(guān)研究，再次印證了這種“多孔晶體明星材料”的巨大潛力。MOFs憑借其可設(shè)計的拓?fù)浣Y(jié)構(gòu)、超高比表面積與可調(diào)孔隙率，正顛d覆氣體吸附、催化、藥物遞送等領(lǐng)域，而這一切的基...
INTRODUCTIONTheN-α-Fmoc-α-aminoisobutyricacidderivative（Aib）isadifficultderivativeforcouplinginSPPSduetoitssecondmethylgroupontheα-carbonthatinterfereswiththecouplingreaction（Figure1）.However,itcanbefoundinanumberofbiologicallyrelevantcompo...
查看詳情INTRODUCTIONTheAKR/Grossmurineleukemiaviruses（MuLV）areC-typeretrovirusesthatcausethedevelopmentofleukemiainAKR（H-2k）mice.1Type-specificantiretroviralcytotoxicT-lymphocyte（CTL）responseshavebeenreportedthatallowdifferentiationbetweeninfection...
查看詳情INTRODUCTIONInthedevelopmentofantibodiesdirectedagainstspecificpeptidesequences,T-helperepitopesareoftentaggedontothepeptidesequencetoaidinthestimulationoftheimmuneresponse.OnesuchsequenceistheuniversalPanHLADR-bindingepitope（PADRE）.Synthes...
查看詳情INTRODUCTIONOnechallengefacingpeptidesynthesisisthe-lactamformationofarginine（Figure1）.Theformationof-lactamoccurswhentheinternalnitrogenoftheguanidineattackstheactivatedester,irreversiblyformingthelactamring.Thisreactioniscompetitivewithpe...
查看詳情INTRODUCTIONOnepotentialissueinpeptidesynthesisisracemizationofcysteineａndhistidine.Thisisaconcernformicrowavepeptidesyntheisbecauseoftheelevatedtemperaturesduringdeprotectionａndcoupling.Studieshaveshownthatloweringthetemperatureto50°Cdurin...
查看詳情INTRODUCTIONVIP（vasoactiveintestinalpeptide）,apeptidehormone,hasbeenimplicatedinanumberofbiologicalprocessesincluding:increasingdigestivesystemmotility,stimulatingpepsinogensecretion,controllingthemammaliancircadiantimekeepingmachinery,regu...
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